57Fe MÖSSBAUER EFFECT STUDIES OF ErFe11Ti AND ErFe11TiH COMPOUNDS

Piotr Gaczyñski1, Irina S. Tereshina2, Vyacheslav S. Rusakov2, Sergej A. Nikitin2, Henryk Drulis1

1Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 2 Okólna Str., 50-950 Wroc³aw, Poland,
2Physics Department of Moscow State University, 119 899, Moscow, Russia


Ferromagnetic compounds ErFe11TiHx (x = 0, 1) have been investigated by 57Fe Mössbauer spectroscopy in the temperature range 20–300 K. Mössbauer spectra were analysed in terms of a model which takes into account the local environment of Fe atoms on three crystallographic sites (8f, 8j and 8i) and an influence of the random distribution of titanium on the 8i site. The 14 sextets with different intensities have been considered. The temperature dependencies of hyperfine interaction parameters and subspectra contributions were derived from experimental spectra. The hyperfine fields and the isomer shift increasing upon hydrogenation are discussed in terms of the hydrogen-induced Wigner-Seitz unit cell expansion and the s-electrons transfer from Fe atoms to the adjacent hydrogen atoms.