NUKLEONIKA 2006, 51(Suppl. 2):s81-s85
Anna Makowska, Jerzy Szyd³owski
Department of Chemistry, University of Warsaw,
101 ¯wirki i Wigury Str., 02-089 Warsaw, Poland
Densities, kinematic viscosities, speed of sound and refractive indices of nitromethane and 1-pentanol
and their deuterated derivatives CD3NO2 and C5H11OD were
measured. The data obtained allowed to calculate molar volumes, dynamic viscosities, isentropic
compressibilities and isobaric thermal expansion. Deuterium isotope effect on the selected
physicochemical properties of both nitromethane and 1-pentanol has been determined. Large isotope
effects characterizing density, viscosity and speed of sound are observed for nitromethane and much
smaller for 1-pentanol. Isotope effects on molar volume are small both for nitromethane and
1-pentanol, but of the opposite sign. These observations are in agreement with the expectations.