NUKLEONIKA 2007, 52(2):59-67
Yongxia Sun1, Andrzej G. Chmielewski1,2, Sylwester Bułka1, Zbigniew Zimek1, Henrieta Nichipor3
1 Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland
2 Faculty of Chemical and Process Engineering, Warsaw University of Technology,
1 L. Waryńskiego Str., 00-645 Warsaw, Poland
3 Institute of Radiation Physical and Chemical Problems of the Belarussian Academy of Sciences,
Minsk-Sosny, Belarus
On the basis of the experimental results, computer simulations of decomposition of dichloroethylenes for three isomers
(trans-DCE, cis-DCE, 1,1-DCE) in air under electron beam were carried out. Computer code “Kinetic” and “Gear” method
were used. Calculation results well agree with the experimental results. Decomposition efficiency of DCE is mainly determined
by Cl- dissociated secondary electron attachment, followed by Cl radical addition reaction with DCE.